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91.
《International Journal of Hydrogen Energy》2022,47(36):16132-16143
In our earlier study, it has been shown that trace Na additions can improve the reaction kinetics of Mg–5%La (wt.%) alloys during the first absorption. However, the subsequent hydrogen desorption/absorption process of the Mg–5%La after the first absorption has not been investigated. In this study, we have investigated the hydrogen sorption behaviour of the Mg–5%La alloy after the first absorption in terms of phase evolution, and lattice expansion properties during desorption as function of temperature using in-situ synchrotron Powder X-ray Diffraction (PXRD) and in-situ High Voltage Transmission Electron Microscopy (HVTEM). Two distinct phase evolutions, a continuous phase transformation of LaH3 → LaH2 + ½ H2 (from 250 °C) and decomposition of MgH2 → Mg + H2 (between 440 and 460 °C) were identified during the desorption. It is determined that this alloy is cyclable in the absence of Mg12La intermetallic during the subsequent absorption/desorption cycling after the first hydrogen absorption. 相似文献
92.
《Ceramics International》2022,48(8):10911-10920
A novel MoSi2–Al2O3 composite coating was prepared on Mo-based TZM alloy by slurry sintering method. The oxidation behavior of the coating was evaluated at 1600 °C in static air. Microstructure and phase composition of the as-prepared and oxidized coatings were characterized, and the antioxidant mechanism of the coating at high temperature was discussed. A three-layer structure was observed in the as-prepared coating, consisting of a ~2 μm thick Mo5Si3 diffusion layer, a ~65 μm thick MoSi2 inner layer and a ~36 μm thick outer layer of mixture of MoSi2 and Al2O3. After oxidation at 1600 °C for 5 h, all MoSi2 phases were completely converted to intermediate silicide Mo5Si3 by solid-state diffusion, and the formed Mo5Si3 phase would be transformed into Mo3Si phase with further extending the oxidation time. Furthermore, a dense oxide layer of SiO2-mullite was formed on the specimen surface, which can effectively protect the material to further oxidation. The MoSi2–Al2O3 coating could protect the substrate effectively at 1600 °C for 20 h without failure. The enhanced oxidation resistance of MoSi2–Al2O3 coating is due to the formation of multi-layer structure containing a SiO2-mullite composite oxide outer layer with high thermal stability and low oxygen permeability. 相似文献
93.
《Calphad》2020
The sodium pyrovanadate (Na4V2O7) powder was synthesized by solid-state reaction using sodium carbonate (Na2CO3) and vanadium pentoxide (V2O5) as raw materials. X-ray powder diffraction (XRD), scanning electron microscope (SEM), and differential scanning calorimeter (DSC) were used to accurately characterize the synthesized sample. The solid-state phase transformation from α-Na4V2O7 to β-Na4V2O7 occurs at the temperature 696 K and the enthalpy is equals to 1.03 ± 0.01 kJ/mol, the endothermic effect at 931 K and the enthalpy is equals to 31.35 ± 0.31 kJ/mol, which is related to the melting of Na4V2O7. The high-temperature heat capacity of Na4V2O7 was measured using a Multi-high temperature calorimeter 96 line and DSC. The obtained high-temperature heat capacity of Na4V2O7, as a function of temperature, was modeled as: Cp=314.62+0.05T-5494390T-2 J·mol-1·K-1 (298.15-873 K). The temperature dependence on heat capacity was then used for computing changes in the enthalpy, entropy, and Gibbs free energy at the specific temperature internal. 相似文献
94.
In the ultra-precision manufacturing of large optics, industrial robots have the potential to become an intelligent and economical choice of surface polishing. However, the transport of the workpieces between the polishing platform and the measurement instrument seriously limits the manufacturing efficiency. Therefore, an in-situ measurement system based on the monoscopic deflectometry is developed to determine the form quality of the optical lenses during rough polishing. Stray light reflected from the lower surface of transparent lenses may degrade the measuring quality, thus an effective absolute phase retrieval algorithm is developed to decouple the superposed fringes associated with the upper and lower surfaces. Then, the form of the upper surface under polishing can be reconstructed to guide the subsequent polishing. Experimental results demonstrate that the accuracy of the method is comparable to that of the coordinate measuring machine, consequently the manufacturing efficiency and reliability of large optical workpieces can be greatly improved. 相似文献
95.
V.I. Popkov O.V. Almjasheva V.N. Nevedomskiy V.V. Panchuk V.G. Semenov V.V. Gusarov 《Ceramics International》2018,44(17):20906-20912
Formation and structural transformations of yttrium orthoferrite crystals have been studied using X-ray diffractometry, Mössbauer spectroscopy and transmission electron microscopy combined with electron microdiffraction. Said processes have been studied under heat treatment of glycine-nitrate combustion products. There have been identified formations of three structural yttrium orthoferrite modifications – amorphized hexagonal <h1>-YFeO3 (P63cm) and nanocrystalline hexagonal h2-YFeO3 (P63/mmc), as well as nanocrystalline orthorhombic o-YFeO3 (Pbnm), which are selectively formed depending on available three-dimensional confinements. Based on the analysis of changes in the fluid and size composition formulation, it has been proposed mechanism for formation and transformation of YFeO3 nanocrystals, including growth stage of h2-YFeO3 crystals due to amorphized phase of <h1>-YFeO3 up to critical size of about 15?nm and their subsequent transformation into orthorhombic form o-YFeO3. 相似文献
96.
Chao Chen Bo Feng Shujuan Hu Yue Zhang Song Li Longfei Gao Xuemei Zhang Kun Yu 《Ceramics International》2018,44(1):216-224
Aluminum phosphate (AlPO4) is a promising oxidation-resistant and weak interface for ceramic-matrix composites. In this research, AlPO4 coating was deposited on mullite fibers by an improved liquid-phase method based on electrostatic attraction. A cationic polyelectrolyte, polyethylenimine (PEI), was used for surface modification of mullite fibers. The formation process, phase evolution and microstructure of the coating were studied. The zeta potential of AlPO4 particles, PEI-adsorbed AlPO4 particles, and PEI-adsorbed mullite particles was characterized to find the proper pH value for improving electrostatic attraction. The obtained AlPO4 coating was porous and continuous, whose thickness could be controlled by multiple coating cycles. The relatively low calcination temperature (600 or 1000 °C) was a useful heat treatment method to develop bonding between coating and fiber as well as reduce the fiber strength degradation. The phase transformations of AlPO4 have little volume change, and cristobalite AlPO4 is thermal compatible with mullite. Therefore, the coating structure was preserved after calcining at 1200 °C. The technique is also applicable for other fibers contained mullite phase to fabricate high-performance AlPO4 coated mullite/mullite composites. 相似文献
97.
Based on multiphase field conception and integrated with the idea of vectorvalued phase field, a phase field model for typical allotropic transformation of solid
solution is proposed. The model takes the non-uniform distribution of grain boundaries of
parent phase and crystal orientation into account in proper way, as being illustrated by the
simulation of austenite to ferrite transformation in low carbon steel. It is found that the
misorientation dependent grain boundary mobility shows strong influence on the
formation of ferrite morphology comparing with the weak effect exerted by
misorientation dependent grain boundary energy. The evolution of various types of grain
boundaries are quantitatively characterized in terms of its respective grain boundary
energy dissipation. The simulated ferrite fraction agrees well with the expectation from
phase diagram, which verifies this model. 相似文献
98.
The aim of this work is the design of a pitot probe (PP) prototype in order to retard the cool down of the tip, in case of a heating element failure. The viability of operation in flight conditions is evaluated. The design consists of a redundant heating system incorporating phase change materials (PCM). Combining experimental observations of ice formation with the implementation of the conjugate heat transfer (CHT) model, with the addition of the heat release due to the phase change of the PCM, the numerical evaluation is developed. The modelling assumptions and numerical implementation of the phase change process are presented. Then, the selection an appropriate PCM is based on the low flammability and volume dilation and the quantitative effects of the material properties on the heat transfer. A commercial PCM solution based on salt hydrates was chosen as the most adequate for the design. The parametric design of the prototype, based on the design of experiment method and fractional factorial testing, is established. A multiple linear regression model was obtained in order to maximize the cooling retardation. The numerical simulations demonstrate that the prototype PP tip temperature remains 194 s longer above 0 °C than that of the conventional model analyzed. 相似文献
99.
This work proposes a novel design method for generalized order lead/lag compensators. With respect to the traditional lead/lag compensator, it introduces a new parameter, β, which is a non-integer number. A new design method of the compensator is introduced in order to quantify its design parameters. Compared to its integer order counterpart, the generalized order lead compensator facilitates with the unique solution of desired design specifications with maximum phase at the desired gain cross-over frequency to achieve reshaping of the loop frequency domain characteristics. On the other hand, generalized order lag compensator is designed so as to allow minimum phase lag at the new gain crossover frequency. Examples with simulation and real-time results are presented to validate the efficacy of the proposed approach. 相似文献
100.
Yong Jiang Zhenbang Wei Wenzhou Sun Limeng Liu Zhenkun Huang 《Ceramics International》2021,47(6):7588-7592
Samples in Si–Al-R-O-N (R = Y, Gd, Yb) systems were prepared by solid-state reactions using R2O3, Al2O3, SiO2 and Si3N4 powders as starting materials. X-ray diffraction was done to investigate RAM-J(R) solid solutions [RAM = R4Al2O9, J(R) = R4Si2N2O7] formation and their equilibrium with RSO (R4Si2O10). Phase relations between RAM, J(R) and RSO at 1700 °C were summarized in a phase diagram. It was determined that a limited solid solution of RAM and RSO could be formed along RAM-RSO tie-line, while RAM and J(R) form a continuous solid solution along RAM-J(R) tie-line. In RAM-J(R)-RSO ternary systems, the RAM-J(R) tie-lines were extended towards the RSO corner to form a continuous solid solution area of JRAMss (R = Y, Gd, Yb). The established phase relations in the Si–Al-R-O-N (R = Y, Gd, Yb) systems may facilitate compositional selections for developing JRAMss as monolithic ceramics or for SiC/Si3N4 based composites using the solid-solutions as a second refractory phase. 相似文献